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Organotrifluoroborate Preparation, Coupling and Hydrolysis
Buch
Buch
Fachbuch
2016

Organotrifluoroborate Preparation, Coupling and Hydrolysis

ISBN
EAN
978-3-319-37734-6
9783319377346
Artikel-Nr.
WRGW6RE
Kostenloser Versand
Rabatt
-10.5
%
CHF 140.00
CHF
125.27
Anzahl
1
Maximale
Lieferzeit
20
Arbeitstage
Mittwoch
14.09.2022
speech-bubble-svg Beschreibung
Alistair Lennox's thesis reports on the reactivity of organotrifluoroborates, which are becoming increasingly important reagents in synthesis. The thesis is divided into three sections. The first section describes a method for preparing organotrifluoroborates. The second section reports on a mechanistic investigation into the main application of RBF3K reagents as coupling partners in Suzuki-Miyaura coupling, phenomena identified as arising from organotrifluoroborate hydrolysis and fluoride release. The final section reports on a detailed investigation into the hydrolysis mechanism, a prerequisite for their Suzuki-Miyaura coupling, and how it may be predicted and controlled. This research has uncovered many interesting and useful details and shows how problems associated with Suzuki-Miyaura coupling can best be addressed. There has already been wide industrial uptake of the new procedures and insights. The broad nature and clear and succinct style will make the thesis a valuable resource for anyone working in synthesis, organometallic chemistry, or in homogeneous catalysis.
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Stichwörter
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Research
Inhaltsverzeichnis
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General Introduction.- Organotrifluoroborate Preparation.- Organotrifluoroborate Coupling.- Organotrifluoroborate Hydrolysis.- Conclusions and Future Work.- Experimental: General Experimental Details.- Experimental: Organotrifluoroborate Preparation.- Experimental: Organotrifluoroborate Coupling.- Experimental: Organotrifluoroborate Hydrolysis.
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Autor/-in
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Publikation
Schweiz
23.08.2016
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Sprache
Englisch
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Buch (Softcover)
223 Seiten
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Passende Themen
Unterkategorie
Organische Chemie
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Unterkategorie
Physikalische Chemie
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