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Buch (Softcover): Fachbuch
Molecular Design of Tautomeric Compounds
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Springer Verlag Unsere-Artikel-Nr.: 3WVRND5
EAN: 9789401071406
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Zustellung: Di, 09.06.2026
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Beschreibung
1. The Problem of Tautomerism. - 1. Tautomerism as Dynamic Isomerism. - 2. Degenerate Tautomerism. - 3. Methods for Investigating Tautomeric Systems. - 4. Butlerov's and Laar's Tautomeric Systems. - 5. Tautomerism and the Mechanisms of Organic Reactions. - 6. Classification of Tautomeric Reactions. - 7. Conclusion. - References. - 2. Carbonotropy. - 1. The Problem of Carbonotropy. - 2. Sigmatropic Acyl and Aryl Rearrangements. - 3. Acylotropic Tautomerism. - 4. Tautomeric Rearrangements of Aryl Groups. - 5. Carbonotropic Tautomerism in Ions, Radicals and Cyclopolyenes. - References. - 3. General Principles of the Design of Tautomeric Systems. - 1. Possibilities of Quantum Mechanical Prediction of Tautomeric Reactions. - 2. Stereochemical Approach to the Design of Tautomeric Compounds. - References. - 4. The Mechanisms of Nucleophilic Substitution at the Main Group Element and Design of Intramolecular Tautomeric Systems. - 1. Tautomeric Rearrangements of Carbon-containing Groups. - 2. Silylotropic Tautomerism. - 3. Tautomeric Migrations of Phosphorus-containing Groups. - 4. Tautomeric Rearrangements of As-containing Groups. - 5. Tautomeric Rearrangements of Sulfur-containing Groups. - References. - 5. Dyotropic and Polytropic Tautomeric Systems. - 1. Scope and Definition. - 2. The Mechanism and Energetics of the Dyotropic Reactions. - References. - 6. Dissociative and Photochemical Mechanisms of Intramolecular Tautomerism. - 1. Heterolytic Dissociative Mechanism. - 2. Homolytic Dissociative Mechanism. - 3. Ion-Radical Mechanism. - 4. Photo-Initiated Carbonotropic Rearrangements. - References.
Spezifikationen
Sprache
- Englisch
Autor
- V. I. Minkin
- Yu. A. Zhdanov
- L. P. Olekhnovich
Kollektion
- Understanding Chemical Reactivity
Erscheinungsjahr
- 2011
Erscheinungsland
- Niederlande
Format
- Buch (Softcover)
Anzahl Seiten
- 296